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trans-Chloridobis(4-methyl-pyridine-κN)(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine-κN,N',N'')ruthenium(II) hexa-fluoridophosphate acetone monosolvate

Redford, Christopher ; Gimbert-Suriñach, Carolina ; Bhadbhade, Mohan ; Colbran, Stephen B

Acta crystallographica. Section E, Structure reports online, 2012-03-01, Vol.68 (Pt 3), p.m300-m300

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  • Title:
    trans-Chloridobis(4-methyl-pyridine-κN)(4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine-κN,N',N'')ruthenium(II) hexa-fluoridophosphate acetone monosolvate
  • Author: Redford, Christopher ; Gimbert-Suriñach, Carolina ; Bhadbhade, Mohan ; Colbran, Stephen B
  • Is Part Of: Acta crystallographica. Section E, Structure reports online, 2012-03-01, Vol.68 (Pt 3), p.m300-m300
  • Description: The title compound, [RuCl(C(6)H(7)N)(2)(C(27)H(35)N(3))]PF(6)·C(3)H(6)O, was obtained unintentionally as the product of the reaction of 1,1'-methyl-enebis(4-methyl-pyridinium) hexa-fluoriso-phos-phate and RuCl(3)(tpy*) (tpy* is 4,4',4''-tri-tert-butyl-2,2':6',2''-terpyridine) in the presence of triethyl-amine and LiCl. The mol-ecular structure of the complex displays an octa-hedral geometry around the Ru(II) ion and the unit cell contains an acetone solvent mol-ecule and one orientationally disordered PF(6) (-) anion (occupancy ratio 0.75:0.25) which is hydrogen bonded to two H atoms of the tpy* ligand of the nearest [RuCl(pic)(2)(tpy*)](+) cation (pic is 4-methyl-pyridine). One of the tert-butyl groups of the tpy* ligand is also disordered over two sets of sites in a 0.75:0.25 ratio.
  • Publisher: United States
  • Language: English
  • Identifier: EISSN: 1600-5368
    DOI: 10.1107/S1600536812005594
    PMID: 22412442
  • Source: © ProQuest LLC All rights reserved

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