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A self-assembled Cofacial cobalt porphyrin prism for oxygen reduction catalysis.(Report)

Amanda N. Oldacre ; Alan E. Friedman ; Timothy R. Cook

Journal of the American Chemical Society, Feb 1, 2017, Vol.139(4), p.1424 [Peer Reviewed Journal]

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  • Title:
    A self-assembled Cofacial cobalt porphyrin prism for oxygen reduction catalysis.(Report)
  • Author: Amanda N. Oldacre ; Alan E. Friedman ; Timothy R. Cook
  • Subjects: Oxygen – Chemical Properties ; Oxidation-Reduction Reactions – Usage ; Catalysis – Usage ; Electrochemistry – Research
  • Is Part Of: Journal of the American Chemical Society, Feb 1, 2017, Vol.139(4), p.1424
  • Description: The article reports the study of the oxygen reduction reaction (ORR) catalyzed by a cofacial porphyrin scaffold accessed in high yield using coordination-driven self-assembly with no chromatographic purification steps. Cyclic voltammetry is used to initially probe the electrochemical catalytic behavior. Rotating ringudisk electrode studies are completed to probe the Faradaic efficiency and an estimate of the rate constant associated with the ORR is obtained.
  • Language: English
  • Identifier: ISSN: 0002-7863
  • Source: Cengage Learning, Inc.

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